C persons exposed to hydrogen sulfide pose no serious risks of secondary. Standard free energy of formation of several metal sulfides and oxides at 1,000 c. Hydrogen sulfide corrosion in lowno x combustion systems. Pdf thermodynamic study of hydrogen sulfide corrosion of mild. The interior surface of the sample exhibited a coating of. One reason why sulfidic corrosion sulfidation is receiving much more emphasis is the. Hydrogen sulfide corrosion of c arbon and stainless steel alloys in. Continuous fixed area monitors can be permanently installed in locations where the sudden release of hydrogen sulfide is possible. Protection of metal from the hydrogen sulfide corrosion. Biogenic sulfide corrosion attacks materials such as steel and concrete. The bare copper tubing was split in half to reveal the extent of internal corrosion as a result of natural gas flow during the 52week exposure period. No part of this manual can be reproduced or transmitted in any form or by any means, electronic, mechanical or otherwise.
Pdf sulfide stress corrosion cracking and hydrogen. The atmospheric corrosion of copper by hydrogen sulphide. The atmospheric corrosion of copper by hydrogen sulphide has been followed during field tests using different sulphide concentrations, for 77 days, and during exposure to a welldefined synthetic atmosphere in a test chamber. Fes corrosion products formation and hydrogen uptake in. Download fulltext pdf download fulltext pdf thermodynamic study of hydrogen sulfide corrosion of mild steel article pdf available in corrosion houston tx 704. Abstracthydrogen sulfide h2s is the most dangerous element which exists in oil and gas reservoir. In the oil and gas industry, the presence of h2s gas might induce sulfide stress cracking. Hydrogen sulfide oxidation and sewer corrosion including the articles. Cathodic protection a technique used to reduce corrosion by making the material act as a cathode, while having a second material in direct contact that is more easily oxidized, which acts as the anode and the site of corrosion. Different from variation of the corrosion potential with the immersion time in the h 2 s free solution, the change rate of corrosion potential with time in the acidic solution with h 2 s. Carbonyl sulfide cos, which occurs as an impurity in commercial sources of propane, can hydrolyze in the presence of water to form hydrogen sulfide h2s and carbon dioxide co2.
Hydrogen sulfide uptake rates and biomass concentration of microorganisms from corroded concrete spring 2009 mark kalhoj department of biotechnology, chemistry and. From kinetic data we obtained evidence for a dissociative adsorption of hydrogen sulfide. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. Hydrogen sulfide hydrogen sulfide h 2 s cas 77830604. Hydrogen sulfide h2s is aggressive gas, provoking acid corrosion, which in. Hydrogen sulfide corrosion in sanitary sewers effected by flow velocities the reduction, elimination, or control of hydrogen sulfide h 2s should be the goal of all designers of sanitary sewer systems.
The mechanism of the catalytic oxidation of hydrogen sulfide. High temperature hydrogen sulfide corrosion of carbon steel and low chrome alloys has become a serious problem in the petroleum industry in connection with the increasing use of high pressure hydrogenation and dehydrogenation processes for upgrading petroleum fractions. Sanitary wastes contain a variety of organic and sulfur compounds. Hydrogen sulfide is a chemical compound with the formula h 2 s, and is often a colorless gas with a rotten egg odor, commonly referred to as sewer gas. Hydrogen sulfide gas also is found in petroleum and natural gas.
Pdf thermodynamic study of hydrogen sulfide corrosion of. The roles of h2s gas in behavior of carbon steel corrosion. Sulfides present in aqueous solution are responsible for stress corrosion cracking scc. Ardent services, llc safety manual page 5 of 8 document no s ossspp0074 hydrogen sulfide h 2 program. Josop 500 hydrogen sulfide program and procedure 6 profile of employees should be updated every three years.
Mild steel is a popular structural steel in this industry but is susceptible to surface scale formation and associated corrosive action, the prevention of which requires some. Different from variation of the corrosion potential with the immersion time in the h 2 s free solution, the change rate of corrosion potential with time in the acidic. Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related activities. Hydrogen sulfide corrosion in wastewater collection and. Hydrogen sulfide gases are generated within the anaerobic slime layer formed on the submerged pipe walls. Sulfur may be present as elemental sulfur s, hydrogen sulfide h2s, mercaptans. On the basis of some esr mea surements we proposed that sulfur radicals are the sites for oxygen chemisorption. Prolonged exposure to h2s can weaken and corrode pipes, leading to a leak or exposure incident. An increase in the partial pressure of hydrogen sulfide aggravates the catastrophic breakdown of carbon steel, yet diminishes both the corrosion rate and the localization of corrosion attack on aluminum alloys.
Design manual sulfide and corrosion prediction and control. Currently, this model is capable of predicting uniform corrosion of carbon steel at a single point in an environment containing carbon dioxide, acetic acid, oxygen, andor hydrogen sulfide. Because of the initial low flow and the long distance hence a long retention time of approximately 30 days in the pipe, the wsa was concerned about the generation of hydrogen sulfide gas in the force main and microbialinduced corrosion. Sources of hydrogen sulfide hydrogen sulfide is formed by sulfur and sulfatereducing bacteria that can occur naturally in water. Table 3 change in standard gibbs free energy of several important reactions during the corrosion. In accordance with the literature, high free fatty acid contents lead to high corrosion rates accounted for direct corrosion of high alloy steels and assisted. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body. Corrosion of iron and steel by hydrogen sulfide forms a black precipitate ferrous sulfide that can stain laundry and bathroom fixtures, darken silverware and discolor copper and brass utensils. The influence of hydrogen sulfide on corrosion of iron. Hydrogen sulfide stress corrosion cracking in materials. Mechanistic study of the effect of iron sulfide layers on hydrogen sulfide corrosion of carbon steel conference paper pdf available in nace international corrosion conference series 2015. Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments.
Hydrogen sulphide corrosion of carbon and stainless steel alloys immersed in mixtures of renewable fuel sources and tested under coprocessing conditions. Pdf hydrogen sulphide corrosion of carbon and stainless. Thermodynamic study of hydrogen sulfide corrosion of mild steel. Hydrogen sulfide is soluble in certain polar organic solvents, notably methanol, acetone, propylene carbonate, sulfolane, tributyl phosphate, various glycols, and glycol ethers hsdb, 1998. Sulfur deposits in the pores of porous materials and causes an autocataly tic effect. Copper tubing evaluation in a natural gas environment.
Corrosion of metal and concrete is a major issue associated with the generation and oxidation of hydrogen sulfide. Hydrogen induced corrosion material science 112 group research paper march 12th, 2001 matthew avery. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage. Traditional conformal coatings used to protect electrical circuits often cannot prevent formation of silver sulfide. Hydrogen sulfide analyzer operation manual proprietary rights notice this manual contains valuable information and material developed by arizona instrument llc for use with the jerome 631x hydrogen sulfide analyzer. These two changes show the remarkable acceleration of hydrogen sulfide to the iron corrosion. Some people can smell hydrogen sulfide at very low levels, as low as 0. H2s corrosion, carbon steel, oil and gas environment.
You can rely on your nose to detect the presence of h2s. The corrosionelectrochemical behavior of both carbon steel and aluminum alloys in hydrogen sulfidebearing mineralized media is considered. Employees assigned to work in areas where exposure or possible exposure to hydrogen sulfide hazards exists will be required to monitor the immediate work area with a fixed field monitor or by utilizing a personal h2s monitor. Natural gas can contain up to 28 percent hydrogen sulfide gas, so it may be an air pollutant near natural gas production areas and. The biogenic sulfide corrosion process occurs when sulfates present in the environment.
Hydrogen sulfide is a relatively common, frequently lethal, and unique occupational hazard for which research since 1990 has uncovered many anomalies and subtleties and. Most hydrogen sulfide in the air comes from natural sources. Design manual sulfide and corrosion prediction and control mclaren, frederick r on. Effect of hydrogen on iron and steel during production, fabrication, and use. All commercial and hd5 grade propane is required to pass the copper strip corrosion test, astm test method d 1838. It has the odor of rotten eggs at extremely low concentrations, less than 2 ppm. The main components formed at the surface of the samples are copper oxides and sulphide. Under lownox substoichiometric combustion conditions, sulfur in coal is released mostly as h2s gas, which will sulfidize boiler tubes at furnacewall temper. A variety of corrosion prevention compounds cpcs were compared for their ability to protect thin silver films from forming silver sulfide corrosion products when exposed to battelle. Hydrogen sulfide is a colorless gas and has a strong odor of rotten eggs hsdb, 1998. While it is known that hydrogen sulfide will cause the failure of the copper strip test, it is. Area monitoring and source measurements should be conducted on need basis, by line management.
Although the copper strip corrosion test is a very crude, qualitative indicator, a correlation between our kinetics measurements with the rate measurements. Since the discovery and development of oil and gas fields containing hydrogen sulfide in the production wells, the problem of protection of metal from the hydrogen sulfide corrosion arose acutely. Description of the hydrogen sulfide induced corrosion of concrete sewer systems a new approach. The monitor sensors should be placed in proximity to potential sources of a hydrogen sulfide release. Mechanism of sulfide corrosion hydrogen sulfide corrosion can occur by two mechanisms. Sulfide may be possible shall participate in the identification, evaluation, and control of hydrogen sulfide hazards. Hydrogen sulfide is a colorless gas with a rottenegg odor. Pdf mechanistic study of the effect of iron sulfide. Corrosion induced by sulfide dissolved free sulfides h 2 s, hs. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing.